Ink is a combination of pigment, resin, solvents, and additives mixed together to form a fluid or paste capable of printing from a printing press. Every ink system is built around three core components:
- Colorants — provide optical properties and fastness
- Binders (polymers, resins & liquid components) — control printability and drying
- Additives — deliver specific performance properties
Types of Printing Ink
Printing ink splits into two broad families:
Paste Ink — used for Letterpress, Offset, Metal, and Silk printing
Liquid Ink — used for Flexographic and Rotogravure printing
Paste Ink / Offset
Common applications include business cards, brochures, packaging boxes, labels, and commercial print (CMYK process printing). Key pigment selection criteria for paste/offset inks:
- Oil absorption
- Transparency
- Flow
- Gloss
- Acid and alkali resistance
- Heat stability
Liquid Ink
Liquid ink splits further by printing process:
Flexographic — Water-based or Alcohol-based systems (commonly used for paper products, plastic bags, and woven sack bags)
Rotogravure — split into:
- Publication (Maleic) inks
- Flexible Packaging inks — using resin systems like Polyamide, Vinyl, NC, CIPP, and PU
Flexible Packaging: Resin Selection
| Resin System | Characteristic |
|---|---|
| Vinyl / EVA | Economical inks; lower printability and gloss vs. PU |
| PU / Vinyl | Good printability and gloss, but more expensive |
| CLPP | Generally used for printing on oven/bag sacks |
| Polyamide | Generally used for gloss |
| NC (Nitrocellulose) | Used where heat resistance is required |
Flexible packaging inks are further categorized by Reverse Printing (printed on the inside of a laminate — bond strength & transparency preferred) and Surface Printing (printed on the outer surface — needs good scratch, nail, rub, and deep-freeze resistance, with gloss being very important).
Sample Ink Formulations
Liquid Ink – Gravure (Polyamide system)
- Pigment: 9 parts
- Polyamide: 70 parts
- Toluene: 16 parts
- N-Butanol: 3 parts
- Luwax A.F-32: 1 part
- Dispersing & Wetting Agent: 1 part
Flexographic Ink (Water-based)
- Joncryl 671 varnish: 30 parts
- Pigment: 30 parts
- Water: 30 parts
- Disperse BYK193: 1.5 parts
- Leveling agent: 0.5 parts
- Mono Ethylene Glycol: 3 parts
- Antifungal agent: 0.4 parts
- Water: 4.6 parts
Flexographic Ink (Solvent-based)
- Pigment: 9 parts
- Polyamide: 80 parts
- Iso Propyl Alcohol: 7 parts
- N-Butanol: 3 parts
- Luwax A.F-32: 1 part
Key Properties of Ink
- Viscosity/Flow — affected by pigment-resin interaction, moisture, pigment-pigment interaction, solvent drying speed, and temperature
- Transparency — depends on printing type and requirement
- Migration/Retort — critical for food packaging; tested at 130°C for 30 minutes on nylon film
- Color Strength — visual/instrumental comparison against standard
- Print Density — measured with a density meter; dot gain affects final image quality
- Gloss — measured optically at 20°, 60°, and 90° angles using a glossmeter
- Fineness of Grind — assessed with a grindometer (paste inks) or under microscope (liquid inks)
- Resolubility — tested by applying ink on metal plate or PET film and checking solvent reactivation
Souring Test
Used to check the effect of moisture on PU/Polyamide resin systems — 0.1%, 0.5%, and 1% water is added to the final ink, and viscosity, color, opacity & gloss are checked on the same day and after 1 week.
Soap Resistance Test
Used for inks in soap wrapper printing — a 10% soap jelly is prepared, ink panel strips are placed on it, and staining is observed after 24 hours.
Common Printing Problems & Root Causes
| Problem | Cause |
|---|---|
| Shade Variation | Adding/mixing too many colors/pigments |
| Fading | Resin/pigment used |
| Settling | Dispersing agent, low viscosity resin, excess solvent |
| Gelling | Wrong solvent / moisture content |
| Skinning | Fast-drying solvents |
| Viscosity issues | Resin / excess solvent |
| Spotting | Slow-drying solvents |
| Tacking | Slow-drying solvents |
| Back Impression | Pigment / slow-drying solvent |
| Cell Blocking | Non-grinding of pigments, fast-drying solvents |
| Lining | Metal content in pigment, non-filtering of ink |
| Odour | Additives, MF, resin, solvents |
| Drying issues | Solvents |
| Delamination | Gum, pigment, resin, additives |
Source: Technical Training – Basic Introduction to Inks, Prashant Nigade / Sudatech, Oct 2019